By C. Bradley Moore
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Instrum. 5,971. HAGEN, W. , and MAGNANTE, P. C. (1969). J. Appl. Phys. 40, 219. HAMADANI, S. , and MAGYAR, G. (1971). Opt. Commun. 4,310. 26 STEPHEN R. LEONE AND C. BRADLEY MOORE HANNA, D. , and SMITH, R. C. (1973). Appl. Phys. Lett. 22,440. HANSCH, T. W. (1972). Appl. Opt. 11,895. HARRIS, S. E. (1969). Proc. IEEE 57,2096. HARRIS, S. , and WALLACE, R. W. (1970). Laser Focus 6(11),42. HARRIS, S. , and WALLACE, R. W. (1972). 5. HARVEY, A. F. (1970). " Wiley (Interscience), New York. HELLWARTH, R.
1972). Appl. Opt. 11,895. HARRIS, S. E. (1969). Proc. IEEE 57,2096. HARRIS, S. , and WALLACE, R. W. (1970). Laser Focus 6(11),42. HARRIS, S. , and WALLACE, R. W. (1972). 5. HARVEY, A. F. (1970). " Wiley (Interscience), New York. HELLWARTH, R. W. (1963). Phys. Rev. 130, 1850. HERBST, R. , and BYER, R. L. (1972). Appl. Phys. Lett. 21,189. HERCHER, M. (1965). Appl. Phys. Lett. 7, 39. HERCHER, M. (1969). Appl. Opt. 8,1103. HODGSON, R. , and DREYFUS, R. W. (1972). Phys. Rev. Lett. 28, 536. -L. (1972).
For example a chain of ten amino acid residues would in principle have ten carbonyl stretching vibrations. However, they will differ in frequency only to the extent that the environments of the carbonyl bonds differ and to the extent that the carbonyl modes couple kinematically with other modes. In practice many polypeptides show only one Raman band in the carbonyl stretching region. When a polypeptide chain consists of identical repeating units, then the number of normal modes is limited to the number expected for the atoms in one repeating unit.