By Tim F. Liebert, Thomas J. Heinze, and Kevin J. Edgar (Eds.)
content material: CONTENTS; ways FOR THE DISSOLUTION OF CELLULOSE; 1. Cellulose Solvents - impressive background, shiny destiny; TIM LIEBERT; 2. layout of Polar Ionic beverages To Solubilize Cellulose with no Heating; YUKINOBU FUKAYA, KENSAKU HAYASHI, SEUNG SEOB KIM AND HIROYUKI OHNO; three. Advances in Aqueous Cellulose Solvents; ANG LUE AND LINA ZHANG; four. Molten Inorganic Salts as response Medium for Cellulose; S. FISCHER AND ok. THUMMLER; five. Dimethyl Sulfoxide and Ammonium Fluorides - Novel Cellulose Solvents; THOMAS HEINZE AND SARAH KOHLER; interplay OF SOLVENTS WITH CELLULOSE; 6. Hydrogen Bond Acceptor houses of Ionic drinks and Their impression on Cellulose Solubility; M. SELLIN, B. ONDRUSCHKA AND A. STARK; 7. at the particular Behaviour of local Cellulose Fibers upon Dissolution; N. LE MOIGNE AND P. NAVARD; eight. facet Reactions within the approach Cellulose/1-Alkyl-3-methyl-imidazolium Ionic Liquid; MICHAEL SCHREMS, GERALD EBNER, FALK LIEBNER, ERNST BECKER, ANTJE POTTHAST AND THOMAS ROSENAU; nine. Cellulose Solubility: Dissolution and research of "Problematic" Cellulose Pulps within the Solvent method DMAc/LiCl; UTE HENNIGES, SONJA SCHIEHSER, THOMAS ROSENAU AND ANTJE POTTHAST; 10. comparability of Solution-State houses of Cellulose Dissolved in NaOH/Water and in Ionic Liquid (EMIMAc); T. BUDTOVA, M. EGAL, R. GAVILLON, M. GERICKE, T. HEINZE, T. LIEBERT, C. ROY, okay. SCHLUFTER AND P. NAVARD; eleven. facets of the interplay of local and artificial Polymers with Direct Dissolving drinks; B. KOSAN, ok. SCHWIKAL, S. HESSE-ERTELT, A. NECHWATAL, F. HERMANUTZ AND F. MEISTER; 12. impact of Enzymatic therapy on Solubility of Cellulose in 7.6%NaOH-Water and Ionic Liquid; PETER ROSENBERG, TATIANA BUDTOVA, MONIKA ROM AND PEDRO FARDIM; adjustments OF CELLULOSE utilizing SOLVENTS; thirteen. Non-Halide Ionic drinks for Solvation, Extraction, and Processing of Cellulosic fabrics; MICHAEL HUMMEL, GERHARD LAUS, ALEXANDER SCHWARZLER, GINO BENTIVOGLIO, EGON RUBATSCHER, HOLGER KOPACKA, KLAUS WURST, VOLKER KAHLENBERG, THOMAS GELBRICH, ULRICH J. GRIESSER, THOMAS RODER, HEDDA ok. WEBER,; HERWIG SCHOTTENBERGER AND HERBERT SIXTA; 14. homes of Cellulose/TiO2 Fibers Processed from Ionic beverages; MIRELA L. MAXIM, NING solar, RICHARD P. SWATLOSKI, MUSTAFIZUR RAHMAN, ADAM G. HARLAND, ANWARUL HAQUE, SCOTT ok. SPEAR, DANIEL T. DALY AND ROBIN D. ROGERS; 15. Novel Cellulose items ready by way of Homogeneous Functionalization of Cellulose in Ionic beverages; SUSANN DORN, MICHAEL SCHOBITZ, KERSTIN SCHLUFTER AND THOMAS HEINZE; sixteen. Dissolution of Cellulose in Ionic beverages and Its program for Cellulose Processing and amendment; LIU CHUANFU, solar RUNCANG, ZHANG AIPING AND LI WEIYING; 17. Imidazolium established Ionic drinks as Solvents for Cellulose Chemistry; JURGEN VITZ, TINA ERDMENGER AND ULRICH S. SCHUBERT; 18. Structure-Property courting of Cellulose Ethers - impact of the artificial Pathway on Cyanoethylation; B. VOLKERT, W. WAGENKNECHT AND M. MAI; 19. possibilities with wooden Dissolved in Ionic beverages; HAIBO XIE, ILKKA KILPELAINEN, ALISTAIR KING, TIMO LESKINEN, PAULA JARVI AND DIMITRIS S. ARGYROPOULOS; 20. Advances in Cellulose Solvent- and natural Solvent-Based Lignocellulose Fractionation (COSLIF); Y.-H. PERCIVAL ZHANG, ZHIGUANG ZHU, JOE ROLLIN AND NOPPADON SATHITSUKSANOH; INDEXES; writer INDEX; topic INDEX
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Additional resources for Cellulose Solvents: For Analysis, Shaping and Chemical Modification
D. Chem. Commun. 2007, 2025. 164. ; Ajayan, P. ; Linhardt, R. J. J. Biomed. Mater. , Part B: Appl. Biomater. 2006, 79, 298. 165. ; Ajayan, P. ; Linhardt, R. J. Biomacromolecules 2006, 7, 415. 166. ; Rogers, R. D. Green Chem. 2009, 11, 646. 167. Tan, S. S. ; MacFarlane, D. ; Edye, L. ; Doherty, W. O. ; Patti, A. ; Pringle, J. ; Scott, J. L. Green Chem. 2009, 11, 339. 168. ; Argyropoulos, D. S. J. Agric. Food Chem. 2007, 55, 9142. 169. ; Guo, M. Biomacromolecules 2004, 5, 266. 170. ; Barthel, S. Macromol.
E. there are no covalent bonds observed by 13C NMR studies. It was concluded from 13C and 35/37Cl-NMR experiments (144, 145) on BMIMCl solutions that the chloride anion is much more involved in the disruption of the hydrogen bond system than the cation comparable to the interaction cellulose/DMAc/LiCl (see below) (140). Still, this finding cannot explain the fact that only ILs with nitrogen-containing cations are able to give clear solutions. No measurements are known for ILs with acetate as counter-ion, which dissolve cellulose even better than the chloride (146, 147).
Barthel, S. Macromol. Biosci. 2005, 5, 520. 171. ; He, J. Cellulose 2009, 16, 299. 172. ; Heinze, T. Macromol. Rapid Commun. 2006, 27, 1670. 173. ; Kilpelaeinen, I. Cellulose 2008, 15, 481. 174. Liu, C. ; Sun, R. ; Zhang, A. ; Ren, J. ; Wang, X.